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It is shallow, so the needle only travels a short distance, and it has fewer pain-sensitive nerves than deeper tissue, so most people feel a small pinch rather than a deep ache

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The mechanism formally parallels the β-elimination reaction catalyzed by PLP-dependant enzymes which accept cysteine thioethers as substrates and likely play a role in the renal toxicity and carcinogenicity of halogen-alkenes through their urinary metabolites [125]